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. Author manuscript; available in PMC: 2014 Jan 1.
Published in final edited form as: J Inorg Biochem. 2012 Oct 5;118:191–200. doi: 10.1016/j.jinorgbio.2012.09.023

Table 4.

Gibbs free energy barriers in HNO reactions with RSH [81].

R 3G≠(kcal/mol) 3G≠(kcal/mol)
pathway A pathway B
H 22.2 26.0
CH3 19.8 13.6
CF3 11.8 34.7
Ph 24.9 15.1
Cys 23.0 ~10