Table 3.
No. | Compound | KIa | Concentration (ppm)b ± standard error | ||||||
---|---|---|---|---|---|---|---|---|---|
| |||||||||
‘Kosui’ | ‘Nijisseiki’ | ‘Niitaka’ | ‘Yakumo’ | ‘Kaori’ | ‘Ya li’ | ‘La France’ | |||
1 | ethyl 2-methypropanoate | 943 | 0.002 ± 0.001 | ndc | 0.002 ± 0.002 | ndc | 0.035 ± 0.002 | 0.054 ± 0.008 | ndc |
2 | methyl 2-methylbutanoate | 1008 | 0.016 ± 0.001 | <0.001 | <0.001 | ndc | 0.002 | 0.001 ± 0.001 | ndc |
3 | ethyl butanoate | 1033 | 0.013 ± 0.009 | 0.006 ± 0.003 | 0.039 ± 0.035 | 0.062 ± 0.021 | 4.190 ± 0.725 | 4.117 ± 0.482 | 0.140 ± 0.021 |
4 | ethyl 2-methylbutanoate | 1047 | 0.001 ± 0.001 | ndc | 0.001 ± 0.001 | ndc | 0.069 ± 0.011 | 0.126 ± 0.019 | ndc |
5 | butyl acetate | 1065 | 0.008 ± 0.001 | 0.011 ± 0.001 | 0.009 ± 0.001 | 0.006 ± 0.001 | 0.017 ± 0.002 | 0.120 ± 0.008 | 30.722 ± 3.660 |
6 | hexanal | 1072 | 0.217 ± 0.008 | 0.145 ± 0.024 | 0.228 ± 0.067 | 0.236 ± 0.059 | 0.406 ± 0.088 | 1.194 ± 0.126 | 0.360 ± 0.056 |
7 | ethyl pentanoate | 1127 | 0.003 | <0.001 | <0.001 | 0.003 ± 0.001 | 0.028 ± 0.001 | 0.027 ± 0.002 | 0.009 ± 0.001 |
8 | pentyl acetate | 1170 | ndc | ndc | ndc | ndc | <0.001 | 0.001 | 0.346 ± 0.057 |
9 | trans-2-hexenal | 1212 | 0.151 ± 0.014 | 0.025 ± 0.004 | 0.099 ± 0.024 | 0.038 ± 0.014 | 0.112 ± 0.022 | 0.170 ± 0.009 | 0.341 ± 0.073 |
10 | ethyl hexanoate | 1234 | 0.004 ± 0.002 | 0.002 | 0.007 ± 0.006 | 0.001 ± 0.001 | 0.165 ± 0.034 | 0.495 ± 0.090 | 0.002 ± 0.002 |
11 | hexyl acetate | 1273 | 0.025 ± 0.012 | ndc | ndc | ndc | 0.029 ± 0.002 | 0.034 ± 0.005 | 16.797 ± 3.826 |
| |||||||||
No. | Concentration (ppm)b ± standard error | ||||||||
| |||||||||
‘Fuji’ | i0009 | i1302 | i01701 | ‘Sanenashi’ | i0187 | i0193 | i0218 | i0471 | |
| |||||||||
1 | 0.001 ± 0.001 | 0.113 ± 0.022 | 0.011 ± 0.003 | 0.150 ± 0.026 | 0.006 ± 0.003 | ndc | 0.029 ± 0.001 | 0.001 ± 0.001 | ndc |
2 | 0.001 ± 0.001 | 0.016 ± 0.004 | 0.003 | 0.034 ± 0.011 | 0.017 ± 0.003 | 0.008 | 0.008 ± 0.002 | 0.001 ± 0.001 | 0.007 |
3 | 0.174 ± 0.014 | 4.006 ± 0.623 | 0.989 ± 0.357 | 4.015 ± 0.189 | 1.112 ± 0.359 | 0.029 ± 0.004 | 1.862 ± 0.763 | 0.119 ± 0.012 | 0.256 ± 0.125 |
4 | 0.001 ± 0.001 | 0.472 ± 0.095 | 0.043 ± 0.008 | 0.601 ± 0.124 | 0.025 ± 0.013 | 0.005 ± 0.002 | 0.179 ± 0.010 | 0.001 ± 0.001 | 0.033 ± 0.021 |
5 | 0.215 ± 0.006 | 0.287 ± 0.031 | 0.248 ± 0.029 | 0.134 ± 0.014 | 1.621 ± 0.408 | 0.033 ± 0.002 | 0.017 ± 0.009 | 0.055 ± 0.025 | 0.028 ± 0.014 |
6 | 0.014 ± 0.001 | 0.256 ± 0.009 | 0.397 ± 0.034 | 0.817 ± 0.091 | 0.955 ± 0.157 | 2.195 ± 0.230 | 1.149 ± 0.338 | 0.871 ± 0.114 | 1.440 ± 0.188 |
7 | 0.011 ± 0.001 | 0.033 ± 0.002 | 0.038 ± 0.011 | 0.039 ± 0.001 | 0.019 ± 0.003 | 0.003 | 0.004 ± 0.002 | 0.022 ± 0.002 | ndc |
8 | 0.007 ± 0.001 | 0.008 ± 0.001 | 0.004 ± 0.001 | 0.005 ± 0.002 | 0.012 ± 0.005 | 0.001 ± 0.001 | <0.001 | ndc | ndc |
9 | 0.468 ± 0.043 | 0.718 ± 0.089 | 0.803 ± 0.100 | 2.126 ± 0.011 | 2.171 ± 0.383 | 2.846 ± 0.217 | 1.669 ± 0.047 | 1.052 ± 0.505 | 0.905 ± 0.085 |
10 | 0.003 ± 0.002 | 2.730 ± 0.521 | 0.606 ± 0.224 | 1.673 ± 0.203 | 0.136 ± 0.071 | 0.008 ± 0.005 | 0.262 ± 0.052 | 0.002 ± 0.002 | 0.035 ± 0.025 |
11 | 0.038 ± 0.001 | 0.254 ± 0.019 | 0.078 ± 0.027 | 0.263 ± 0.021 | 0.177 ± 0.052 | 0.003 ± 0.003 | 0.046 ± 0.020 | 0.011 ± 0.006 | 0.026 ± 0.003 |
| |||||||||
No. | Concentration (ppm)b ± standard error | ||||||||
| |||||||||
i0605 | i0830 | i0868 | i0959 | i0981 | i1003 | i1104 | i1115 | ||
| |||||||||
1 | 0.063 ± 0.010 | ndc | 0.031 ± 0.005 | 0.004 | 0.021 | 0.106 ± 0.007 | 0.022 | 0.007 ± 0.001 | |
2 | 0.022 ± 0.002 | 0.002 ± 0.001 | 0.039 ± 0.008 | ndc | 0.001 ± 0.001 | 0.018 ± 0.003 | 0.004 | ndc | |
3 | 3.660 ± 0.617 | 0.341 ± 0.066 | 1.332 ± 0.015 | 0.198 ± 0.038 | 0.921 ± 0.064 | 3.782 ± 0.583 | 0.568 ± 0.102 | 0.740 ± 0.007 | |
4 | 0.477 ± 0.058 | 0.027 ± 0.008 | 0.215 ± 0.009 | 0.012 ± 0.001 | 0.089 ± 0.005 | 0.259 ± 0.065 | 0.065 ± 0.011 | 0.024 ± 0.005 | |
5 | 3.171 ± 0.644 | 1.840 ± 0.022 | 0.323 ± 0.065 | 0.133 ± 0.030 | 0.949 ± 0.019 | 3.480 ± 0.413 | 0.015 ± 0.001 | 0.631 ± 0.055 | |
6 | 0.001 | 0.066 ± 0.021 | 0.201 ± 0.033 | 0.342 ± 0.076 | 0.787 ± 0.315 | 1.041 ± 0.576 | 1.603 ± 0.432 | 1.599 ± 0.081 | |
7 | ndc | ndc | 0.028 ± 0.003 | 0.001 ± 0.001 | 0.021 ± 0.001 | 0.043 ± 0.006 | 0.003 ± 0.001 | 0.008 ± 0.001 | |
8 | 0.034 ± 0.005 | 0.020 ± 0.002 | 0.009 ± 0.001 | 0.002 ± 0.001 | 0.007 ± 0.006 | 0.079 ± 0.008 | ndc | 0.006 ± 0.001 | |
9 | 0.216 ± 0.096 | 0.664 ± 0.089 | 1.791 ± 0.395 | 0.560 ± 0.178 | 0.950 ± 0.067 | 1.795 ± 0.701 | 2.474 ± 0.752 | 1.870 ± 0.011 | |
10 | 3.105 ± 0.543 | 0.087 ± 0.023 | 0.545 ± 0.019 | 0.064 ± 0.011 | 0.395 ± 0.080 | 1.304 ± 0.220 | 0.124 ± 0.003 | 0.229 ± 0.015 | |
11 | 0.982 ± 0.143 | 0.723 ± 0.087 | 0.107 ± 0.014 | 0.026 ± 0.007 | 0.129 ± 0.005 | 3.292 ± 1.376 | 0.004 ± 0.001 | 0.253 ± 0.040 |
KI means Kovats Index calculated for the DB-Wax capillary column (60 m × 0.25 mm i.d.).
Mean values (±SE) obtained from experiments performed twice in duplicate were calculated.
nd: not detected due to too low peak or no peak.