Table 3.
particle size <63 μm |
particle size ≥63 and <150 μm |
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Element | MDLa | DF (%)b | GMc,d | GSDc,e | Range | DF (%)b | GMc,d | GSDc,e | Range |
Be* | 0.003 | 100 | 0.23 | 1.29 | 0.13-0.31 | 100 | 0.13 | 1.66 | 0.04-0.23 |
B | 0.011 | 100 | 22.52 | 2.16 | 7.93-122.32 | 100 | 18.27 | 2.47 | 6.17-123.92 |
Na | 0.006 | 100 | 3505.00 | 3.20 | 813.48-27201.38 | 100 | 3701.06 | 4.05 | 652.63-74493.06 |
Mg | 0.009 | 100 | 3423.43 | 1.27 | 2237.81-4943.84 | 100 | 2107.85 | 1.49 | 1170.59-5022.54 |
Al* | 0.004 | 100 | 7407.65 | 1.37 | 4187.65-12312.75 | 100 | 4144.84 | 1.43 | 1713.32-5959.99 |
Si | 0.005 | 100 | 73.72 | 5.33 | 14.78-1442.14 | 100 | 265.08 | 2.73 | 51.17-1176.96 |
P | 0.150 | 100 | 580.22 | 1.64 | 304.06-1250.45 | 100 | 422.36 | 1.57 | 215.15-1062.61 |
K | 0.006 | 100 | 2387.74 | 1.55 | 1294.72-4245.57 | 100 | 1455.29 | 2.16 | 200.64-2749.19 |
Ca | 0.005 | 100 | 21716.91 | 1.66 | 7371.25-49674.67 | 100 | 11313.25 | 2.15 | 1637.59-24447.65 |
Ti | 0.006 | 100 | 100.64 | 1.87 | 37.10-259.73 | 100 | 57.27 | 1.47 | 32.07-93.09 |
V* | 0.005 | 100 | 10.95 | 1.27 | 7.70-18.78 | 100 | 6.37 | 1.50 | 2.94-9.68 |
Cr | 0.006 | 100 | 37.49 | 2.15 | 14.90-187.06 | 100 | 25.62 | 3.01 | 9.86-483.36 |
Mn | 0.003 | 100 | 198.52 | 1.61 | 107.69-373.24 | 100 | 97.61 | 1.65 | 35.61-167.47 |
Fe | 0.011 | 100 | 6776.86 | 1.28 | 5070.45-10811.94 | 100 | 5275.51 | 1.70 | 2048.99-13466.47 |
Co | 0.002 | 100 | 5.26 | 1.50 | 2.41-8.14 | 100 | 2.91 | 1.56 | 1.57-6.11 |
Ni | 0.005 | 100 | 21.34 | 1.92 | 8.92-51.11 | 100 | 15.19 | 2.38 | 4.13-57.66 |
Cu | 0.003 | 100 | 69.09 | 2.70 | 37.72-958.31 | 100 | 57.32 | 1.70 | 29.70-149.97 |
Zn | 0.002 | 100 | 311.35 | 2.46 | 68.94-1152.34 | 100 | 186.02 | 3.46 | 34.35-2569.10 |
Ge | 0.004 | 100 | 0.06 | 1.20 | 0.04-0.08 | 100 | 0.04 | 1.83 | 0.01-0.07 |
As | 0.003 | 100 | 3.04 | 1.64 | 1.71-7.57 | 100 | 2.03 | 2.52 | 0.56-17.44 |
Se | 0.012 | 100 | 0.64 | 1.85 | 0.31-1.89 | 90 | 0.39 | 5.36 | BDL-2.95 |
Zr | 0.006 | 100 | 37.57 | 3.01 | 8.07-245.32 | 100 | 34.92 | 3.21 | 8.01-407.41 |
Nb | 0.006 | 100 | 0.17 | 1.98 | 0.06-0.46 | 100 | 0.17 | 1.49 | 0.08-0.25 |
Mo* | 0.002 | 100 | 3.17 | 1.42 | 2.13-7.38 | 100 | 1.41 | 1.45 | 0.75-2.50 |
Ag | 0.004 | 100 | 0.89 | 2.53 | 0.23-3.99 | 100 | 0.84 | 2.50 | 0.22-6.17 |
Cd | 0.004 | 80 | 0.15 | 10.54 | BDL-1.16 | 70 | 0.08 | 13.83 | BDL-2.14 |
Sn | 0.009 | 100 | 0.90 | 1.83 | 0.35-2.18 | 100 | 4.47 | 3.78 | 0.78-49.81 |
Sb | 0.009 | 80 | 0.02 | 5.15 | BDL-0.88 | 100 | 0.11 | 3.66 | 0.02-0.57 |
Ba | 0.003 | 100 | 123.07 | 1.54 | 53.10-196.93 | 100 | 65.29 | 1.59 | 35.85-192.45 |
Pb | 0.004 | 80 | 3.11 | 49.47 | BDL-26.32 | 100 | 19.42 | 3.03 | 2.48-147.74 |
MDL – minimum detection limit, BDL – below detection limit
DF – detection frequency
0.5*MDL used for samples <BDL
GM – geometric mean
GSD – geometric standard deviation
indicates signficiance after Bonferroni correction (p<0.0017)