. Author manuscript; available in PMC: 2013 Dec 21.

Published in final edited form as: Angew Chem Int Ed Engl. 2012 Nov 19;51(52):13054–13057. doi: 10.1002/anie.201207820

Table 2.

Rearrangements of 1-sulfonyl triazoles 6 to give substituted alkenes 7. General reaction conditions: 1-sulfonyl triazole (1.0 mmol, 1.0 equiv.), rhodium(II) octanoate (0.5 mol%), CHCl₃ (2.0 mL), 70 °C, mw, 20 – 80 min. All values shown represent isolated yields.

Entry	Triazole	[°C/min]	Product	Yield
1	6a	70/20	7a	91%
2	6b	70/60	7b	96%
3	6c	70/30	7c	92%
4	6d	70/30	7d	96%
5	6e	70/60	7e	92%
6	6f	70/80	7f	71%