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. Author manuscript; available in PMC: 2013 Apr 17.
Published in final edited form as: Acc Chem Res. 2012 May 21;45(8):1321–1330. doi: 10.1021/ar3000019

FIGURE 5.

FIGURE 5

UV–vis spectral changes showing the formation of [Mn(14-TMC)(O2)]+ (2) (red) and the disappearance of [Ni(12-TMC)(O2)]+ (9) (green) by addition of [Mn(14-TMC)]2+ to a solution of 9. Inset shows the spectroscopic titration at 453 nm for the formation of 2 as a function of the equivalents of [Mn(14-TMC)]2+ added to a solution of 9.35