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Optimized reactant and transition state geometries for the reaction of tBu-TFDO with sclareolide 10. Energies are in kcal/mol. Individual components of distortion energies (alkane distortion, dioxirane distortion) are in parenthesis. The prime labels on TS distinguish the transition states for tBu-TFDO oxidation with those with DMDO. Energies with acetonitrile solvation correction are in square brackets.
