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. 2013 Feb 25;14(3):4444–4460. doi: 10.3390/ijms14034444

Table 5.

Content of the K form (%) (in CDCl3 at 303 K), [O] (%) = 100 − [K] (%).

[K] (%) a
1 94.5 (87.0) b
2 77.5 (83.0) c
3 71.0 (72.0) c; 56 d,e[10]
4 59.0 (57.5) c
5 55.5; 50 d,e[10,13]; 51.5 [20]; 20 d,f[12]
6 53.0 (50.0) c
7 48.0; 33 d,e[10]
8 50.5
9 45.5
10 29.5
11 3.5
a

Based on integrals of the H10 signals (present paper);

b

Since the 1H NMR chemical shifts for various tautomers differ insignificantly (see Table 4), contributions based on integrals of the N(CH3)2 protons are not precise;

c

Values in parentheses are based on integrals of the substituent protons;

d

Literature data for chloroform solutions at 298 K;

e

Only K and O tautomers were detected in CDCl3;

f

There are three different forms in CDCl3: [K] + [O] + [E] = 20% + 37% + 43% [12].