Table 5.
Content of the K form (%) (in CDCl3 at 303 K), [O] (%) = 100 − [K] (%).
[K] (%) a | |
---|---|
1 | 94.5 (87.0) b |
2 | 77.5 (83.0) c |
3 | 71.0 (72.0) c; 56 d,e[10] |
4 | 59.0 (57.5) c |
5 | 55.5; 50 d,e[10,13]; 51.5 [20]; 20 d,f[12] |
6 | 53.0 (50.0) c |
7 | 48.0; 33 d,e[10] |
8 | 50.5 |
9 | 45.5 |
10 | 29.5 |
11 | 3.5 |
Based on integrals of the H10 signals (present paper);
Since the 1H NMR chemical shifts for various tautomers differ insignificantly (see Table 4), contributions based on integrals of the N(CH3)2 protons are not precise;
Values in parentheses are based on integrals of the substituent protons;
Literature data for chloroform solutions at 298 K;
Only K and O tautomers were detected in CDCl3;
There are three different forms in CDCl3: [K] + [O] + [E] = 20% + 37% + 43% [12].