Table 4.
31P-NMR chemical shifts of the internal phosphate resonances measured for solutions of ss- and ds-RNA complexed with 3 at different mole ratios.
| 9 | 10 | 9:10 | ||
|---|---|---|---|---|
|
| ||||
| oligo-to-3 mole ratio | Chemical shift δ (ppm) | |||
| ∞1 | −1.220 | −1.201 | −1.207 | −1.590 |
| 10000 | −1.236 | ND | ND | ND |
| 1000 | −1.277 | −1.207 | −1.208 | −1.593 |
| 500 | −1.283 | −1.212 | −1.212 | −1.599 |
| 100 | −1.305 | −1.215 | −1.217 | −1.602 |
| 10 | −1.307 | −1.220 | −1.228 | −1.604 |
The phosphorous NMR of oligonucleotide only.