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. Author manuscript; available in PMC: 2014 Mar 25.
Published in final edited form as: Angew Chem Int Ed Engl. 2013 Feb 19;52(13):3672–3675. doi: 10.1002/anie.201209457

Table 2.

Dehydrogenation of Substituted Cyclohexenones,[a]

graphic file with name nihms457265t2.jpg
Entry Cyclohexenone Phenol Time
[h]		 Yield
[%][b]
1 graphic file with name nihms457265t3.jpg graphic file with name nihms457265t4.jpg 10 90[c]
2 graphic file with name nihms457265t5.jpg graphic file with name nihms457265t6.jpg 10 96[c]
3 36 46
4 6.5 63
5 graphic file with name nihms457265t7.jpg graphic file with name nihms457265t8.jpg 10 87
6 graphic file with name nihms457265t9.jpg graphic file with name nihms457265t10.jpg 24 77
7 24 73
8 12 68
9 graphic file with name nihms457265t11.jpg graphic file with name nihms457265t12.jpg 10 89
10 10 52[c]
11 10 83
[a]

Reactions were performed on 1.0 mmol scale in DMSO/H2O (v/v 0.2/0.05 mL).

[b]

Isolated yield.

[c]

PdII/L5/AMS = 5%/5%/15%.