Table 1. Total N2O emissions from 15 agricultural soils un-amended (control) or mixed with 2% biochar (dry weight basis) under denitrification conditions (90% WFPS and 30°C). Soils were spiked with KNO3 (15N 99% enrichment), which allowed the determination of the total N denitrified (N2 + N2O) and the ratio N2O/(N2 + N2O) by the 15N gas-flux method.
Total N2O produced after 12 days of incubation | Fluxes of N2 and N2O when the difference between biochar and control N2O fluxes was maximum** | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Total cumulative N2O (mg N2O-N kg−1 soil) | Total cumulative N2O respect to initial NO3− in soil (%) | N2 (μmol kg−1 soil h−1) | N2O (μmol kg−1 soil h−1) | N2O/(N2 + N2O) | |||||||
Soil | Control | Biochar | Control | Biochar | Mitigation (%) | Control | Biochar | Control | Biochar | Control | Biochar |
Elba | 120 | 108 | 91.4 | 82.5 | 10 | 2.75 | 3.03 | 17.39 | 17.99 | 0.864 | 0.856 |
Lins | 0.9 | 1.3 | 1.4 | 1.9 | −38 | 0.06 | 0.06 | 2.26 | 0.44 | 0.972 | 0.850 |
Arkport | 2.9 | 1.0 | 4.3 | 1.4 | 67 | 15.77 | 4.82 | 0.54 | 0.09 | 0.053 | 0.038 |
Lentiscosa | 2.1 | 1.5 | 2.6 | 1.8 | 31 | 3.41 | 23.73 | 4.45 | 2.34 | 0.550 | 0.159 |
Tioga | 10.3 | 4.0 | 17.2 | 6.6 | 61 | 0.12 | 0.14 | 1.43 | 0.38 | 0.820 | 0.651 |
Howard | 17.0 | 10.3 | 23.2 | 14.1 | 39 | 1.23 | 2.08 | 7.46 | 9.39 | 0.793 | 0.766 |
Secanos | 12.3 | 3.1 | 8.5 | 2.1 | 75 | 5.23 | 0.76 | 3.64 | 0.61 | 0.443 | 0.394 |
Cabezo | 6.5 | 0.7 | 8.8 | 1.0 | 89 | 10.95 | 4.29 | 1.74 | 0.67 | 0.295 | 0.142 |
Hudson A | 0.4 | 0.3 | 0.7 | 0.6 | 18 | 0.22 | 0.22 | 0.36 | 0.48 | 0.607 | 0.291 |
Madalin | 15.1 | 1.9 | 14.7 | 1.8 | 88 | 0.58 | 0.97 | 3.64 | 0.17 | 0.795 | 0.130 |
Niagara | 23.9 | 6.6 | 18.6 | 5.1 | 72 | 0.41 | 1.06 | 18.53 | 9.10 | 0.971 | 0.854 |
Hudson B | 9.0 | 3.8 | 15.2 | 6.4 | 58 | 3.59 | 4.04 | 7.28 | 4.61 | 0.643 | 0.511 |
Costa | 30.6 | 6.1 | 2.7 | 0.5 | 80 | 7.79 | 14.25 | 5.67 | 2.36 | 0.458 | 0.179 |
Coronela | 69.8 | 7.0 | 12.9 | 1.3 | 90 | 14.49 | 2.26 | 9.99 | 1.47 | 0.468 | 0.244 |
Guarapuava | 3.3 | 0.4 | 4.2 | 0.5 | 89 | 0.17 | 0.09 | 1.63 | 0.14 | 0.782 | 0.447 |
Values are the mean of 4 replicates.