Skip to main content

View full-text article in PMC

. Author manuscript; available in PMC: 2013 Oct 24.

Published in final edited form as: J Am Chem Soc. 2012 Oct 15;134(42):17526–17535. doi: 10.1021/ja304525n

Table 1.

Selected metrical data for [Co^IIMST]⁻, [Co^IIMST(OH₂)]⁻, and [Co^IIIMST(OH₂)].

	[Co^IIMST]⁻	[Co^IIMST(OH₂)]⁻	[Co^IIIMST(OH₂)]
Bond Distances (Å)
Co1–O7	NA	2.135(1)	1.934(2)
Co1–N1	2.114(1)	2.199(1)	1.954(2)
Co1–N2	1.973(1)	2.020(1)	1.950(2)
Co1–N3	1.957(1)	2.028(1)	1.927(2)
Co1–N4	1.971(1)	2.054(1)	1.961(2)
d[Co-N_eq]	0.207	0.310	0.127
Bond Angles (°)
N1-Co1-O7		175.52(5)	178.20(7)
N3-Co1-N4	118.90(5)	119.83(5)	119.48(8)
N4-Co1-N2	117.52(5)	119.28(5)	119.43(7)
N3-Co1-N2	120.31(5)	114.04(5)	118.78(7)