Table 3.
Rate Constants and Half Lives for BQ and BQD on pH 7.4 and 5.5.
| Chemical | ka(s−1) | ks(s−1) | t½(s) | ki(s−1) |
|---|---|---|---|---|
| BQ (pH 7.4) | 1.66 × 103 | 1.50 × 103 | 4.44 × 10−4 | 1.06 × 10−2 |
| BQ (pH 5.5) | 2.61 × 104 | 2.26 × 104 | 3.07 × 10−5 | 6.94 × 10−1 |
|
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| (EDG) pH 7.4 | ||||
| MBQ | 3.87 × 102 | 3.23 × 102 | 2.14 × 10−3 | 5.74 × 10−3 |
| tBBQ | 2.39 × 101 | 2.31 × 101 | 3.00 × 10−2 | 8.06 × 10−4 |
| DMBQ | 7.47 × 10−1 | 7.27 × 10−1 | 9.54 × 10−1 | 2.93 × 10−4 |
|
| ||||
| (EWG) pH 7.4 | ||||
| CBQ | 2.18 × 105 | 2.62 × 105 | 2.64 × 10−6 | 3.78 ×10−1 |
| 2,6-DCBQ | 1.60 × 106 | 1.21 × 106 | 5.74 × 10−7 | 2.98 |
| 2,5-DCBQ | 2.92 × 106 | 2.83 × 106 | 2.45 × 10−7 | 2.99 × 10−1 |
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| ||||
| (EDG) pH 5.5 | ||||
| MBQ | 1.51 × 103 | 1.60 × 103 | 4.34 × 10−4 | 1.71 × 10−3 |
| tBBQ | 3.60 × 102 | 3.37 × 102 | 2.06 × 10−3 | 3.33 × 10−2 |
| DMBQ | 1.05 × 101 | 1.25 × 101 | 5.56 × 10−2 | 1.48 × 10−3 |