Table 1.
δH (700 MHz) and δC (175 MHz) NMR spectra data of M1 and M2 (CD3OD, δ in ppm and J in Hz)
| M1 | M2 | |||
|---|---|---|---|---|
| δC | δH multi (J) | δC | δH multi (J) | |
| 1′ | 133.9 s | 133.87 s | ||
| 2′ | 110.97 d | 6.85 d (7.9) | 110.90 d | 6.82 d (8.0) |
| 3′ | 146.41 s | 146.39 s | ||
| 4′ | 143.68 s | 143.68 s | ||
| 5′ | 114.24 d | 6.74 d (1.8) | 114.23 d | 6.69 |
| 6′ | 120.89 d | 6.71 d (7.9, 1.8) | 120.83 d | 6.64 d (7.9, 1.5) |
| 1 | 31.80 t | 2.64 m 2.73 m |
33.12 t | 2.61 m 2.72 m |
| 2 | 40.06 t | 1.78 m 1.81 m |
39.39 t | 1.84 m |
| 3 | 72.41 d | 3.89 m | 69.57 d | 3.96 m |
| 4 | 42.94 t | 1.64 m | 42.37 t | 1.65 m |
| 5 | 73.40 d | 3.84 m | 68.95 d | 3.91 m |
| 6 | 38.35 t | 1.45 m | 37.48 t | 1.46 m |
| 7 | 25.03 t | 1.30 m | 25.42 t | 1.30 m |
| 8 | 31.44 t | 1.30 m | 31.78 t | 1.30 m |
| 9 | 22.64 t | 1.30 m | 22.59 t | 1.30 m |
| 10 | 14.07 q | 0.91 t (7.2) | 14.02 q | 0.89 t (7.2) |
| 1″ | 55.87 q | 3.87 s | 55.85 q | 3.87 s |