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. Author manuscript; available in PMC: 2013 May 13.
Published in final edited form as: Chem Rev. 2008 Nov;108(11):10.1021/cr800443h. doi: 10.1021/cr800443h

Table 1.

Examples of the diversity of biominerals. This list is by no means comprehensive, where some 70 different mineral phases have been identified to date.111

Biogenic Minerals Formula Organism Biological Location Biological Function
Calcium Carbonates
(calcite, vaterite, aragonite, Mg-calcite, amorphous)
CaCO3
(Mg,Ca)CO3
CaCO • nH2O
Many marine organisms, Aves, Plants
Mammals
shell, test, eye lens, crab cuticle, eggshells, leaves inner ear exoskeleton, optical, mechanical strength, protection, gravity receptor, buoyancy device, Ca store
Calcium Phospates
(hydroxylapatite, dahllite, octacalcium phosphate)
Ca10(PO4)6(OH)2
Ca5(PO4,CO3)3(OH)
Ca8H2(PO4)6, ?
Vertebrates
Mammals
Fish, Bivalves
bone, teeth, scales, gizzard plates, gills mitochondria endoskeleton, ion store, cutting/grinding, protection, precursor
Calcium Oxylates
(whewellite, wheddellite)
CaC2O4 • H2O
CaC2O4 • 2H2O
Plants
Fungi
Mammals
leaves
hyphae
renal stones
protection/deterrent, Ca
storage/removal, pathological
Iron Oxides
(magnetite, goethite, lepidocrocite, ferrihydrite)
Fe3O4
α-FeOOH, γ-FeOOH
5Fe2O3 • 9H2O
Bacteria, Chitons
Tuna/salmon
Mammals
intracellular, teeth, head, filaments, Ferritin protein magnetotaxis, magnetic orientation, mechanical strength, iron storage
Sulfates
(gypsum, celestite, barite)
CaSO4 • 2H2O
SrSO4
BaSO4
Jellyfish

Acantharia
Loxodes, Chara
statoconia
cellular
intracellular statoliths
gravity receptor
skeleton
gravity device/receptor
Halides
(flourite, hieratite)
CaF2 Mollusc, Crustacean gizzard plate
statocyst
crushing
gravity perception
Sulfides
(pyrite, sphalerite, wurtzite, galena, greigite)
FeS2
ZnS, PbS
Fe3S4
Thiopneutes cell wall sulfate reduction/ion removal?
Silicon oxides
(silica)
SiO2 • nH2O Diatoms
Radiolaria
Plants, etc.
cell wall
cellular
leaves
exoskeleton
skeleton
protection