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. Author manuscript; available in PMC: 2014 Apr 19.
Published in final edited form as: J Org Chem. 2013 Apr 10;78(8):4107–4114. doi: 10.1021/jo400428m

Table 2.

Reactions of structurally varied amines wtih 6.a

entry amine product time yieldb
graphic file with name nihms463032t1.jpg graphic file with name nihms463032t2.jpg
1 R = H 5 h 90%
2 R = Me 3 h 97%
3 R = OMe 24 h 94%
4 R = Cl 18 h 99%
5 graphic file with name nihms463032t3.jpg graphic file with name nihms463032t4.jpg 72 h 12%c
6 graphic file with name nihms463032t5.jpg graphic file with name nihms463032t6.jpg 24 h 97%
7 graphic file with name nihms463032t7.jpg graphic file with name nihms463032t8.jpg 18 h 96%
8 graphic file with name nihms463032t9.jpg graphic file with name nihms463032t10.jpg 36 h 30%c
a

Unless otherwise noted, reactions were conducted using 2 mol% Ru(bpy)3Cl2, 2 equiv of MVK, and 1 equiv of TFA in degassed MeCN (0.25 M) at 50 °C and were irradiated using a 23 W compact fluorescent light bulb at a distance of 30 cm.

b

Values represent the averaged isolated yields of two reproducible experiments unless otherwise noted.

c

Yield determined by 1H NMR using an internal standard.