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. Author manuscript; available in PMC: 2014 Apr 1.
Published in final edited form as: Inorg Chem. 2013 Mar 19;52(7):3597–3610. doi: 10.1021/ic300077g

Table 4.

Optical Properties of BF2bdk/PLA Blends at 0.05% and 0.5% Dye Loadings at 77 K

0.05% BF2bdk/PLA (w/w%) 0.5% BF2bdk/PLA (w/w%)
λF/nma τF/nsb λF/nma τF/nsb
1 412d n/ac 391d n/ac
2 421 2.11 413d 2.19
3 441 2.40 449 3.33
4 418 (524)e weak (9.35)e 418 (531)e 1.54 (10.10)e
5 385 0.64 387 0.84
6 422 2.06 435 2.12
7 434 1.42 425 1.39
8 427 (523)e 1.85 (7.87)e 431 (529)e 2.03 (8.31)e
9 425 1.77 432 1.75
10 426 6.59 409d 7.81
a

Excited with 369 nm LED.

b

Pre-exponential weighted lifetimes. All fluorescence lifetimes were fitted with triple-exponential decays.

c

Signal too weak to be detected with current LED excitation.

d

Excited at 350 nm.

e

Values in parentheses correspond to charge transfer processes.