Model simulations showing that the effects of eCA on surface boundary-layer HCO3− and H+ concentrations are small. A, If CO2 leaks from the cell, eCA can convert this leaked CO2 to HCO3−, but the surface HCO3− concentration increases by less than 1 μm. B, eCA has only a minor effect on the H+ concentration during CO2 uptake. Both panels show results from simulations with T. weissflogii, since the effects of eCA, although still small, are more significant for this species.