ce |
Concentration of 18O-CO2 species in the bulk solution |
mol cm−3
|
MIMS measurement |
cs |
Concentration of 18O-CO2 species in the surface boundary layer |
mol cm−3
|
Modeled |
ci |
Concentration of 18O-CO2 species inside the cell |
mol cm−3
|
Modeled |
be |
Concentration of 18O-HCO3− species in the bulk solution |
mol cm−3
|
Modeled |
bs |
Concentration of 18O-HCO3− species in the surface boundary layer |
mol cm−3
|
Modeled |
bi |
Concentration of 18O-HCO3− species inside the cell |
mol cm−3
|
Modeled |
kuf
|
Uncatalyzed CO2 hydration rate constant |
s−1
|
Background 18O removal rate |
kur
|
Uncatalyzed HCO3− dehydration rate constant |
s−1
|
Background 18O removal rate |
ksf
|
eCA-catalyzed CO2 hydration rate constant |
cm3 s−1
|
eCA assay (this study) |
ksr
|
eCA-catalyzed HCO3− dehydration rate constant |
cm3 s−1
|
eCA assay (this study) |
kcf
|
iCA-catalyzed CO2 hydration rate constant |
s−1
|
iCA assay (Tu et al., 1978)
|
kcr
|
iCA-catalyzed HCO3− dehydration rate constant |
s−1
|
iCA assay (Tu et al., 1978)
|
fc-BL
|
Boundary-layer mass transfer coefficient for CO2
|
cm3 s−1
|
iCA assay (Tu et al., 1978)
|
fb-BL
|
Boundary-layer mass transfer coefficient for HCO3−
|
cm3 s−1
|
iCA assay (Tu et al., 1978)
|
fc-M
|
Membrane mass transfer coefficient for CO2
|
cm3 s−1
|
iCA assay (Hopkinson et al., 2011)
|
fb-M
|
Membrane mass transfer coefficient for HCO3−
|
cm3 s−1
|
iCA assay (Hopkinson et al., 2011)
|
N |
Number of cells in the assay chamber |
– |
Coulter Counter measurement |
Ve
|
Bulk solution volume |
cm3
|
Measured |
Vs
|
Surface layer volume |
cm3
|
Imposed, 8 × 10−12 cm3
|
Vi
|
Intracellular volume |
cm3
|
Coulter Counter measurement |
G |
Stoichiometric matrix describing the hydration of CO2 species to HCO3−
|
– |
Hopkinson et al. (2011) |
H |
Stoichiometric matrix describing the dehydration of HCO3− species to CO2
|
– |
Hopkinson et al. (2011) |