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(a) Synthetic scheme of Phe-OCA monomer and the structure of (BDI-EI)ZnN(TMS)2 catalyst. (b) Schematic illustration of (BDI-EI)ZnN(TMS)2/Cpt mediated ring-opening polymerization (ROP) of Phe-OCA followed by formulation of Cpt-PheLAn nanoconjugates (NCs, n = the feed ratio of Phe-OCA/Cpt) using nanoprecipitation. (c) Chemical structures of hydroxyl-containing paclitaxel, doxorubicin and docetaxel.
