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Eyring plots for the isomerization reactions of [MCl4(NO)(Hind)]−trans to cis (in red) (M = Ru (2) (Δ), Os (4) (○)) and cis to trans (in blue) (M = Ru (1) (◊), Os (3) (□)) in C2D2Cl4. The solid lines are the best fits with activation parameters quoted in Table 4.
