Table 3.
Overall bilayer thicknesses DB (Å) as a function of temperature, hydrocarbon chain length, and the degree of hydrocarbon chain unsaturation. Overall bilayer thickness thermal contractivities and chain length expansivities, αTDB and αncDB, respectively, are also shown. αncDB is calculated for each group of lipids depending on their total number of double bonds (e.g., 0 for DLPG, 1 for POPG, and 2 for DOPG).
20 °C |
30 °C |
50 °C |
60 °C |
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DB | α T DB | α nc DB | DB | α T DB | α nc DB | DB | α T DB | α nc DB | DB | α T DB | α nc DB | |
DLPG | 29.9 | 0.0022 ± 0.0006 | NA | 29.1 | 0.0023 ± 0.0006 | 0.0592 ± 0.0150 | 27.8 | 0.0024 ± 0.0006 | 0.0691 ± 0.0081 | 27.2 | 0.0024 ± 0.0007 | 0.0678 ± 0.0055 |
DMPG | NA | NA | NA | 32.5 | 0.0016 ± 0.0009 | 0.0529 ± 0.0134 | 31.4 | 0.0017 ± 0.0009 | 0.0612 ± 0.0072 | 30.9 | 0.0017 ± 0.0009 | 0.0595 ± 0.0048 |
DPPG | NA | NA | NA | NA | NA | NA | 35.5 | 0.0028 ± 0.0028 | 0.0541 ± 0.0064 | 34.5 | 0.0029 ± 0.0029 | 0.0533 ± 0.0043 |
DSPG | NA | NA | NA | NA | NA | NA | NA | NA | NA | 38.2 | NA | 0.0481 ± 0.0039 |
POPG | 37.3 | 0.0016 ± 0.0006 | 0.0500 ± 0.0289 | 36.6 | 0.0016 ± 0.0006 | 0.0442 ± 0.0289 | 35.5 | 0.0017 ± 0.0006 | 0.0449 ± 0.0288 | 34.9 | 0.0017 ± 0.0007 | 0.0484 ± 0.0289 |
SOPG | 38.8 | 0.0014 ± 0.0006 | 0.0385 ± 0.0278 | 38.2 | 0.0015 ± 0.0006 | 0.0423 ± 0.0277 | 37.1 | 0.0015 ± 0.0006 | 0.0430 ± 0.0276 | 36.6 | 0.0015 ± 0.0007 | 0.0461 ± 0.0276 |
DOPG | 36.3 | 0.0007 ± 0.0006 | NA | 35.7 | 0.0008 ± 0.0006 | NA | 35.1 | 0.0009 ± 0.0006 | NA | 35.0 | 0.0009 ± 0.0006 | NA |