Table 4.
Hydrocarbon thicknesses 2DC (Å) as a function of temperature, hydrocarbon chain length, and the degree of hydrocarbon chain unsaturation. Hydrocarbon thickness expansivities as a function of temperature and hydrocarbon chain length, αT2DC and αnc2DC, respectively, are also shown. αnc2DC is calculated for each group of lipids depending on their total number of double bonds (e.g., 0 for DLPG, 1 for POPG, and 2 for DOPG).
20 °C |
30 °C |
50 °C |
60 °C |
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2DC | α T 2DC | α nc 2DC | 2DC | α T 2DC | α nc 2DC | 2DC | α T 2DC | α nc 2DC | 2DC | α T 2DC | α nc 2DC | |
DLPG | 20.7 | 0.0020 ± 0.0006 | NA | 20.2 | 0.0020 ± 0.0006 | 0.0832 ± 0.0153 | 19.4 | 0.0020 ± 0.0006 | 0.0955 ± 0.0085 | 19.0 | 0.0020 ± 0.0007 | 0.0936 ± 0.0059 |
DMPG | NA | NA | NA | 23.6 | 0.0014 ± 0.0009 | 0.0714 ± 0.0131 | 22.9 | 0.0014 ± 0.0009 | 0.0809 ± 0.0072 | 22.6 | 0.0014 ± 0.0009 | 0.0788 ± 0.0049 |
DPPG | NA | NA | NA | NA | NA | NA | 26.8 | 0.0026 ± 0.0028 | 0.0691 ± 0.0062 | 26.1 | 0.0027 ± 0.0029 | 0.0681 ± 0.0043 |
DSPG | NA | NA | NA | NA | NA | NA | NA | NA | NA | 29.7 | NA | 0.0599 ± 0.0037 |
POPG | 28.3 | 0.0012 ± 0.0006 | 0.0566 ± 0.0290 | 27.8 | 0.0012 ± 0.0006 | 0.0609 ± 0.0292 | 27.1 | 0.0012 ± 0.0006 | 0.0589 ± 0.0291 | 26.7 | 0.0012 ± 0.0007 | 0.0618 ± 0.0291 |
SOPG | 29.9 | 0.0013 ± 0.0006 | 0.0535 ± 0.0275 | 29.5 | 0.0013 ± 0.0006 | 0.0574 ± 0.0276 | 28.7 | 0.0013 ± 0.0006 | 0.0556 ± 0.0275 | 28.4 | 0.0013 ± 0.0006 | 0.0582 ± 0.0274 |
DOPG | 27.9 | 0.0007 ± 0.0006 | NA | 27.5 | 0.0007 ± 0.0006 | NA | 27.2 | 0.0007 ± 0.0006 | NA | 27.1 | 0.0007 ± 0.0006 | NA |