. Author manuscript; available in PMC: 2014 May 3.

Published in final edited form as: J Org Chem. 2013 Apr 17;78(9):4615–4619. doi: 10.1021/jo4005519

Table 1.

Borylation of Various Heterocyclic Halides^a


entry	alkyl halide	product	yield (%)
1		1a	72
2		1b	51
3		2	59
4		3	54
5		4a	27
6		4a	52
7		5	52
8		6	30

Reaction conditions: Halide (1.0 equiv), B₂pin₂ (1.5 equiv), CuI (10 mol %), PS-PPh₃ (13 mol %), MeOLi (2.0 equiv), DMF ([halide] = 0.2 M), rt, 20 h then sat. aq KHF₂ (4.0 equiv), THF, rt, 2 h.