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. Author manuscript; available in PMC: 2014 May 6.
Published in final edited form as: Inorg Chem. 2013 Apr 23;52(9):5006–5012. doi: 10.1021/ic302694y

Figure 2.

Figure 2

Solid-state structures for (a) (PhL)Fe2CoCl(NCCH3) (4), (b) (PhL)FeCO2Cl(NCCH3) (5), and (c) [(PhL)FeCo2(µ-Cl)]2 (6) with the thermal ellipsoids set at the 50% probability level (hydrogen atoms, and solvent molecules omitted for clarity; Fe orange, Co aquamarine, C gray, N blue, O red, Cl green). Bond lengths (Å) for 4: Fe1-M2, 2.5391(7); Fe1-M3, 2.5493(8); M2-M3, 2.2934(8); Fe1-Cl, 2.3393(9); Fe1-NACN, 2.134(3); for 5: Fe1-Co2, 2.5253(6); Fe1-Co3, 2.5348(6); Co2-Co3, 2.2971(5); Fe1-Cl, 2.2348(9); Fe1-NACN, 2.129(3); for 6: Fe1A-Co2A, 2.5120(14); Fe1ACo3A, 2.5319(14); Co2A-Co3A, 2.2860(13); Fe1A-Cl1, 2.349(2), Fe1A-Cl2, 2.441(2); Fe1-Fe1, 3.4474(14); Fe1B-Co2B, 2.5009(14); Fe1B-Co3B, 2.5334(14); Co2B-Co3B, 2.2862(14); Fe1B-Cl1, 2.349(2), Fe1B-Cl2, 2.428(2); Fe1-Fe1, 3.4474(14).