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. Author manuscript; available in PMC: 2014 May 22.
Published in final edited form as: J Am Chem Soc. 2013 May 8;135(20):7567–7571. doi: 10.1021/ja400659s

Table 1.

Pd(II)-Catalyzed ortho-Olefination of Phenol Derivativesa,b

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a

Reaction conditions: 1a–1l (0.1 mmol), 2a (0.2 mmol), Pd(OAc)2 (5 mol %), Boc-Val-OH (10 mol %), KHCO3 (0.2 mmol), O2 (1 atm), t-AmylOH (1 mL), 90 °C, 24h.

b

Isolated yield.

c

Pd(OAc)2 (10 mol %), Boc-Val-OH (20 mol %).