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Hammett Plot of Decarboxylative Palladation. The appropriate substrate was mixed with Pd(O2CCF3)2 (1.2 equiv) in 0.75 mL DMSO-d6 and heated to 50 °C with 1H NMR monitoring. Reaction conditions: initial concentration [6a-c] = 0.066 M and [Pd(O2CCF3)2] = 0.079 M, 0.75 mL DMSO-d6. Equation of the line: y = −1.867x + 0.0029. R2 = 0.999
