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. Author manuscript; available in PMC: 2013 Jun 19.
Published in final edited form as: J Am Chem Soc. 2008 Jan 4;130(4):1440–1452. doi: 10.1021/ja0773507

Scheme 13.

Scheme 13

Generalized Mechanism for the Metal-Catalyzed Synthesis of Furans via Allene Intermediate Involving 1,2-Migration of Different Migrating Groups