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. Author manuscript; available in PMC: 2014 May 17.
Published in final edited form as: Angew Chem Int Ed Engl. 2013 Apr 15;52(21):5594–5598. doi: 10.1002/anie.201209454

Scheme 1.

Scheme 1

Generation of 1 by photolytic cleavage of the C–S bond in 5-(phenylthiomethyl)-2’-deoxyuridine (PhSmdU) as well as thiol addition products in the dinucleotide context.