Table 1. Summary of the examined polymers.
Polymer | Mw (g/mol) | m | n | EO/PO | HLB* |
---|---|---|---|---|---|
P188 | 8400 | 27 | 80 | 8/2 | 29 |
P1107 | 15000 | 20 | 58 | 7/3 | 24 |
PEG-8K | 8000 | 0 | 182 | ∞ | Hydrophilic |
P181 | 1750 | 32 | 2 | 1/9 | 3 |
P333 | 4950 | 60 | 17 | 3/7 | 9 |
P335 | 6500 | 56 | 37 | 5/5 | 15 |
HLB: hydrophile-lipophile balance. For PEO-PPO-PEO copolymers, HLB = -36m/(2n+m)+33, where m represents the number of repeat units in the PPO segment and n represents the number of repeat units in the PEO segment.21 In general, the higher the HLB, the higher the hydrophobicity of the copolymer is.