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. Author manuscript; available in PMC: 2013 Nov 18.
Published in final edited form as: Tetrahedron. 2012 Nov 18;68(46):9307–9343. doi: 10.1016/j.tet.2011.12.070

Scheme 23.

Scheme 23

Conversion of shishisididemniol A (145) to tyramine MTPA esters (153ab), and selected 1H NMR chemical shifts for 153ab, and synthetic models 154ab and 155ab.