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. Author manuscript; available in PMC: 2014 May 8.
Published in final edited form as: J Am Chem Soc. 2013 Apr 24;135(18):6830–6833. doi: 10.1021/ja402916z

Table 2.

Scope of the enantioselective redox-relay Heck reaction of homoallylic alcohols and aryl boronic acids.

graphic file with name nihms-472684-t0007.jpg

Yield are reported as a combination of isomers and reaction performed on 0.5 mmol scale. Enatioselectivity determined SFC equipped with a chiral column.

a

Ratio of γ to β–product as detemined by either 1H NMR or gas chromatography.

b

Enatioselectivity of the β-product is 99:1 er.

c

Reaction performed on 10 mmol scale.