Table 3.
The yield of diphenyl selenide 3aa upon changing the ratio 1a/2a.
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entry | amount of 1a | amount of 2a | yield of 3aaa |
1 | 0.1 mmol | 0.5 mmol | 69% 0.138 mmol |
2 | 0.1 mmol | 0.3 mmol | 69% 0.138 mmol |
3 | 0.1 mmol | 0.1 mmol | 59% 0.118 mmol |
4 | 0.1 mmol | 0.067 mmol (2/3 equiv) |
57% 0.118 mmol |
5 | 0.2 mmol | 0.1 mmol | 88%b 0.263 mmol |
aThe yields were determined by HPLC based on the amount of 1a. bThe yield was calculated based on the amount of 2a.