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. Author manuscript; available in PMC: 2013 Jul 8.
Published in final edited form as: Acc Chem Res. 2007 May 31;40(7):501–509. doi: 10.1021/ar600059h

FIGURE 12.

FIGURE 12

Catalytic cycle involving [FeII(SMe2N4(tren))]+ (2)-promoted reduction of superoxide to afford H2O2, via the sequential protonation and Cp2Co-promoted reduction of hydroperoxo- and solvent-bound intermediates.