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. Author manuscript; available in PMC: 2013 Jul 8.
Published in final edited form as: Acc Chem Res. 2007 May 31;40(7):501–509. doi: 10.1021/ar600059h

FIGURE 5.

FIGURE 5

Low-temperature detection of the hydroperoxo intermediate [FeIII(SMe2N4(tren))(OOH)]+ (3) using electronic absorption spectroscopy, and its conversion to solvent-bound [FeIII(SMe2N4(tren))(OMe)]+ (4) upon warming.