. 2013 Mar 8;5(3):504–523. doi: 10.3390/toxins5030504

Table 1.

Mycotoxins and metabolites detected in the liquid chromatography-mass spectrometry (LC-MS)/ mass spectrometry (MS) analysed samples, specifying the number of positive samples (n (pos)), the percentage of positive samples, as well as the median (positives) and the maximum concentration in μg/kg. In case there were only two positives, the range is provided instead; analytes are listed in order of prevalence.

Mycotoxin/metabolite		n (pos)	% pos	Median (μg/kg)	Max (μg/kg)	Mycotoxin/metabolite		n (pos)	% pos	Median (μg/kg)	Max (μg/kg)
Beauvericin		81	98	6.7	2326	Pestalotin		5	6	10	19
sum of Enniatins		80	96	30	5441	Tetracycline (ab)		5	6	77	10,696
	Enniatin A1	79	95	5.5	2216	Versicolorin C **		5	6	0.8	89
	Enniatin B	76	92	11	780	Amoxycillin * (ab)		4	5	NA	NA
	Enniatin B1	76	92	14	2690	Andrastin D *		4	5	NA	NA
	Enniatin A	72	87	0.8	1745	Dechlorogriseofulvin		4	5	18	182
	Enniatin B2	8	10	0.8	13	Griseofulvin		4	5	31	399
	Enniatin B3	7	8	0.01	0.1	Griseofulvin		4	5	31	399
Deoxynivalenol		74	89	122	25,928	Linamarin (plt)		4	5	1705	20,205
Emodin		74	89	9.8	1570	Monoacetoxyscirpenol		4	5	7.7	31
Equisetin		72	87	23	13,680	Neoxaline		4	5	3.3	13
Zearalenone		72	87	14	5326	Penitrem A		4	5	92	701
Aurofusarin		70	84	85	17,659	Roquefortine C		4	5	103	915
Alternariol methyl ether		68	82	1.4	733	Secalonic acid D		4	5	4.5	369
Alternariol		66	80	2.8	221	3-AcetylDON		3	4	28	588
Tentoxin		66	80	3.9	76	Agroclavin		3	4	0.1	0.9
Moniliformin		63	76	45	12,236	Aminodecyl octadecanol		3	4	39	276
DON-3-glucoside		62	75	15	7764	Cytochalasin J		3	4	27	164
Culmorin		61	63	195	44,616	Ergocorninine		3	4	14	15
Nivalenol		61	63	17	1760	Ergocristine		3	4	47	63
Tryptophol		59	71	267	99,040	Ergocristinin		3	4	21	25
Apicidin		55	66	1.9	160	Ergocryptine		3	4	16	25
Brevianamide F		54	65	69	2043	Ergocryptinine		3	4	8.8	11
Tenuazonic acid		54	65	68	1983	Ergosin		3	4	27	52
15-Hydroxyculmorin		52	63	49	15,620	Ergosinin		3	4	4.8	8.6
Butenolide		43	52	23	1490	Ergotamine		3	4	71	129
ZEN-4-sulfate		41	49	1	136	Ergotaminine		3	4	9.7	18
Altertoxin-I		35	42	1.1	65	Lotaustralin (plt)		3	4	50	435
Curvularin		29	35	14	484	Ochratoxin A		3	4	4.9	31
Avenacin Y		26	31	209	9948	Paspalitrem A *		3	4	NA	NA
Macrosporin A		26	31	3.3	9.1	Rubellin D		3	4	259	1188
T-2 Toxin		26	31	3.8	427	Rubrofusarin		3	4	2374	4923
Macrosporin		24	29	3.7	15	T-2 Tetraol		3	4	9.5	1655
Monocerin		24	29	0.9	2644	sum of Aflatoxins		2	2	0.24 ^a	861
Siccanol *		23	28	9607	39850		Aflatoxin B₁	2	2	0.24 ^a	699
3-Nitropropionic acid		19	23	6	392		Aflatoxin B₂	1	1	-	63
sum of Fumonisins		18	22	203	57,667		Aflatoxin G₁	1	1	-	69
	Fumonisin B₁	18	22	142	40,300		Aflatoxin G₂	1	1	-	4.4
	Fumonisin B₂	18	22	38	10,372		Aflatoxin M₁	1	1	-	26
	Fumonisin B₃	14	17	18	3859	Cyclopiazonic acid		2	2	37 ^a	2319
	Fumonisin B₄	7	8	112	3136	Diacetoxyscirpenol		2	2	0.04 ^a	2.7
Fusaric acid		18	22	643	13,593	Ergocornine		2	2	19 ^a	25
HT-2 Toxin		18	22	13	1910	Ergocristam *		2	2	17,370 ^a	19230
Chrysophanol		17	20	8.2	41	Ergocristinam *		2	2	7181 ^a	8233
Mycophenolic acid		17	20	40	21,856	Ergovalin		2	2	1 ^a	5.4
Averufin **		16	19	0.4	215	Gibberellic acid		2	2	9.7 ^a	89
β-Zearalenol		15	18	5.1	174	Methylsterigmatocystin		2	2	0.4 ^a	27
Bikaverin *		14	17	27510	51,130	Neosolaniol		2	2	0.7 ^a	290
Fusaproliferin		14	17	2555	14,844	Penicillic acid		2	2	12 ^a	13
Fusarinolic acid **		13	16	643	13,965	Radicicol		2	2	5.3 ^a	5.9
Skyrin		13	16	1.4	6853	Terphenyllin		2	2	16 ^a	67
Chlamydosporol		12	14	55	656	15-AcetylDON		1	1	-	2718
5-Hydroxyculmorin		11	13	350	3920	Aflatrem *		1	1	NA	NA
α-Zearalenol		11	13	2	51	Averantin		1	1	-	20
Ergometrinin		11	13	0.3	14	Averufanin **		1	1	-	29
Kojic acid		10	12	75	3172	Calphostin C		1	1	-	431
Chanoclavin		8	10	0.1	8.9	Citrinin		1	1	-	42
Andrastin A *		7	8	4814	7603	Cycloaspeptide A		1	1	-	4.6
Physcion		7	8	245	1162	Cytochalasin B		1	1	-	27
Sterigmatocystin		7	8	1.5	4.7	Cytochalasin H		1	1	-	77
15-Hydroxyculmoron		6	7	83	4886	Decalonectrin		1	1	NA	NA
Aspterric acid		6	7	194	3992	Erginie		1	1	-	0.33
hydrolysed FB₁		6	7	15	95	Festucalvin		1	1	-	0.34
Paspalin *		6	7	NA	NA	Malformin A **		1	1	-	8
Sambucinol		6	7	149	675	Malformin C		1	1	-	2.7
Citreoviridin		5	6	94	382	Nidurufin **		1	1	-	9
Ergometrin		5	6	6.8	26	Norsolorinic acid **		1	1	-	1.6
Lycomycin *		5	6	NA	NA	Pyrenophorol		1	1	-	13
Meleagrin		5	6	237	1821	Rugulosin		1	1	-	201,640
Oxytetracyclin		5	6	NA	NA	T-2 Triol		1	1	-	278
Paxillin		5	6	5017	94,860	Versicolorin A **		1	1	-	27

^a minimum in µg/kg; * no standard available for quantification (if a standard became available at some point, the results samples analysed thereafter are shown in the median/maximum column); ** semi-quantified using response factor of a structurally related analyte; ab: antibiotic, plt: plant metabolite, NA: not applicable.