Table 2.
Transition Example | Process | Rate | Typical Timescale |
---|---|---|---|
| |||
So → S1 | Excitation, Absorption | k(e) | Femtoseconds, 10−15 s |
Internal Conversion | k(ic) | Picoseconds, 10−12 s | |
Vibrational Relaxation | k(vr) | Picoseconds, 10−12 s | |
S1 → S0 (radiative) | Florescence | k(f) | Typically less than 10−8 s |
S1 → S0 (non radiative) | Quenching and other non radiative processes | k(nr), k(q) | 10−7 – 10−5 s |
S1 → T1 | Intersystem Crossing | k(pt) | 10−10 – 10−8 s |
T1 → S0 | Phosphorescence | k(p) | 10−3 – 100 s (earlier literature) > 10−8 s (recent literature) |