Table 2. Arrhenius Parameters for BA-a Monomer Showing the Effect of Purificationa.
BA-a as obtained |
BA-a
recrystallized |
|||||
---|---|---|---|---|---|---|
heating rate (K min–1) | Ea (kJ mol–1) | n | m | Ea (kJ mol–1) | n | m |
5 | 81.4 | 3.04 | 1.30 | 93.7 | 1.95 | 1.17 |
8 | 2.74 | 1.30 | 1.73 | 0.85 | ||
10 | 2.31 | 1.64 | 1.90 | 0.90 | ||
12 | 2.23 | 1.30 | 1.69 | 0.89 | ||
15 | 2.14 | 1.39 | 1.75 | 0.80 |
Activation energy Ea was calculated using the Kissinger method. An autocatalytic model was used to calculate values for n and m.