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. 2013 Jun 26;46(13):5117–5132. doi: 10.1021/ma401014h

Table 2. Arrhenius Parameters for BA-a Monomer Showing the Effect of Purificationa.

  BA-a as obtained
BA-a recrystallized
heating rate (K min–1) Ea (kJ mol–1) n m Ea (kJ mol–1) n m
5 81.4 3.04 1.30 93.7 1.95 1.17
8   2.74 1.30   1.73 0.85
10   2.31 1.64   1.90 0.90
12   2.23 1.30   1.69 0.89
15   2.14 1.39   1.75 0.80
a

Activation energy Ea was calculated using the Kissinger method. An autocatalytic model was used to calculate values for n and m.