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. 2013 Jun 26;46(13):5117–5132. doi: 10.1021/ma401014h

Table 6. Assignments for Selected Key Bands Apparent in the PCA of the Raman Vibrational Spectra.

peak range (cm–1) proposed assignment reference source
1615–1620 C–C stretch in benzene ring (31, 32)
1584–1590 C–C stretch in benzene ring (31)
1575 C–C stretch in benzene ring (31)
1486–1489 C–H bend in CH2 (27, 33)
1451–1455 CH2 scissoring (ring) (26, 27)
1434 CH2 scissoring (ring) (26, 27)
1308–1325 CH2 wag (27, 33)
1285–1288 C–H bridge (31, 33)
1205–1215 C–O–C or possibly C–N–C asymmetric stretch (ring closed) (27)
1192 C–N–C asymmetric stretch (ring closed) (27)
1172–1174 C–H bending (ring) (33)
1118 Wilson 18b (ring closed) (27)
1104 C–N–C symmetric stretch (ring closed) (27)
1049–1052 C–O–C symmetric stretch of ring or during cure (33) (ring), (27) (curing)
1033 C–C stretching vibration of ring (33)
999 C–C bending vibration of ring (27)
860 C–N–C symmetric stretch (ring closed) (27)
745–751 benzoxazine ring breathing (27)