Table 1. Physical properties for conjugated microporous polymers.
CMPs | SBET (m2 g−1)* | Smicro (m2 g−1)† | Vtot (cm3 g−1)‡ | Vmicro (cm3 g−1)§ | Mcalc (wt. %)|| | MICP (wt. %)¶ | CO2 uptake (mg g−1)# |
---|---|---|---|---|---|---|---|
CMP | 772 | 283 | 1.21 | 0.117 | 0 | 0 | 71.0 |
Co-CMP | 965 | 293 | 2.81 | 0.419 | 8.20 | 7.19 | 79.3 |
Al-CMP | 798 | 315 | 1.41 | 0.298 | 4.01 | 3.46 | 76.5 |
Further details are provided in Fig. 4b and Supplementary Fig. S4.
*Brunauer–Emmett–Teller (BET) surface area calculated over the pressure range (P/P0) 0.05–0.3.
†Micropore surface area calculated from the N2 adsorption isotherm using the t-plot method.
‡Total pore volume at P/P0=0.99.
§Micropore volume calculated using the t-plot method.
||Data calculated based on each monomer unit.
¶Data obtained with inductively coupled plasma-optical emission spectroscopy (ICP–OES).
#Volumetric CO2 adsorption–desorption isotherms measured for Co-CMP and Al-CMP at 298 K.