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. Author manuscript; available in PMC: 2014 Apr 17.
Published in final edited form as: J Am Chem Soc. 2013 Apr 3;135(15):5631–5640. doi: 10.1021/ja311166u

Figure 6.

Figure 6

Time resolved spectral changes obtained upon mixing acetonitrile solutions of Mn(II) complex 1 (1.5 mM) and O2 (4.05 mM) at −10 °C. Inset: kinetic trace (λ = 515 nm) showing formation and subsequent decay of the Mn-O2 intermediate 4. All reported concentrations are after mixing in the stopped-flow cell.