Table 1.
Odorant | Uptakea | Retentiontimeb | Partitioncoefficientc,d | Henry'slaw constant |
---|---|---|---|---|
Strongly sorbed odorants | ||||
Methyl benzoate | 0.9 | 1 | * | 1.3e3 |
Benzaldehyde | 0.84 | 0.8 | * | 870 |
Isovaleric acid | * | 10 | 2.9e4 | 2.5e5 |
Menthonee | * | * | * | 210 |
Weakly sorbed odorants | ||||
Heptanal | 0.32 | 0.1 | 9.1e1 | 72 |
Propyl acetatef | * | * | * | 110 |
Amyl acetate | 0.2 | 0.1 | 4e2 | 56 |
Butyl acetate | * | 0.1 | 6.2e2 | 77 |
Methyl valerate | * | * | * | 59 |
Values show different measures of sorption properties for odorants used. The first three columns show different experimental measurements of odorant sorption, measured as uptake (fraction removed from airstream after passage through human nasal cavity), retention time (relative retention time of odorant by frog olfactory epithelium), or partition coefficient (relative partitioning of odorant into water vs airc or mucus vs aird). The fourth column shows water–air partition coefficients calculated as Henry's law constants using the group method in HENRYWIN 3.2 (Environmental Protection Agency) at 25°C. Higher numbers reflect stronger odorant sorption.
*Values not available from experimental literature.