Table 1.
Kd/nM | ΔH/kcal.mol−1 | TΔS/kcal.mol−1 | ΔG/kcal.mol−1 | |
---|---|---|---|---|
pH 5.0 | 1962 ± 485 | −33.43 ± 0.73 | −25.63 ± 0.58 | −7.80 ± 0.15 |
pH 5.5 | 2045 ± 363 | −31.01 ± 0.68 | −23.23 ± 0.57 | −7.77 ± 0.11 |
pH 6.0 | 806 ± 77 | −25.26 ± 0.30 | −16.94 ± 0.25 | −8.32 ± 0.06 |
pH 6.5 | 311 ± 30 | −22.49 ± 0.65 | −13.60 ± 0.70 | −8.89 ± 0.06 |
pH 7.0 | 236 ± 27 | −18.71 ± 0.46 | −9.67 ± 0.39 | −9.05 ± 0.07 |
pH 7.5 | 186 ± 16 | −14.34 ± 0.31 | −5.15 ± 0.25 | −9.19 ± 0.05 |
pH 8.0 | 149 ± 15 | −4.53 ± 0.34 | +4.80 ± 0.28 | −9.32 ± 0.06 |
The binding stoichiometries to the fits agreed to within ±10%. Errors were calculated from at least three independent measurements. All errors are given to one standard deviation.