Table 3.
Kd/nM | ΔH/kcal.mol−1 | TΔS/kcal.mol−1 | ΔG/kcal.mol−1 | |
---|---|---|---|---|
pH 5.0 | 5456 ± 1079 | −21.39 ± 0.61 | −14.20 ± 0.50 | −7.19 ± 0.12 |
pH 5.5 | 3860 ± 645 | −20.39 ± 0.40 | −12.99 ± 0.29 | −7.40 ± 0.10 |
pH 6.0 | 3736 ± 1076 | −14.87 ± 0.57 | −7.45 ± 0.74 | −7.42 ± 0.17 |
pH 6.5 | 2177 ± 696 | −9.37 ± 0.33 | −1.63 ± 0.14 | −7.75 ± 0.19 |
pH 7.0 | 192 ± 18 | −5.57 ± 0.20 | +3.75 ± 0.14 | −9.17 ± 0.06 |
The binding stoichiometries to the fits agreed to within ±10%. Errors were calculated from at least three independent measurements. All errors are given to one standard deviation.