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. Author manuscript; available in PMC: 2014 Jun 17.
Published in final edited form as: Angew Chem Int Ed Engl. 2013 May 2;52(25):6508–6512. doi: 10.1002/anie.201301601

Scheme 2.

Scheme 2

A) Two chair conformers of the tris-coordinated gold carbene with L1 as the bidentate ligand. B) Ortep drawing of L5AuCl with the solvent molecules omitted. C) L9 with two chair conformers. D) The structure of L10.