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. Author manuscript; available in PMC: 2014 Jun 19.
Published in final edited form as: J Am Chem Soc. 2013 Jun 4;135(24):8798–8801. doi: 10.1021/ja4033549

Table 1.

Faradaic efficiencies (FE) and current densities for electrocatalytic reduction of CO2 to CO at an applied potential of −1.95 V vs. SCE in MeCN.

Electrode Ionic Liquid FECO jco (mA/cm2)
GCE [EMIM]BF4 Trace <0.03a
Bi-CMEC [EMIM]BF4 93 ± 7 % 3.77 ± 0.7
Bi-CMEC None 48 ± 13% 0.11 ± 0.1
Bi-CMEC [BMIM]BF4 95 ± 6% 5.51 ± 1.2
Bi-CMEC [BMIM]PF6 90 ± 9% 4.82 ± 0.7
Bi-CMEC [BMMIM]BF4 76 ± 6% 0.67 ± 0.5
a

Total current density