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. 2013 May 17;52(24):6283–6287. doi: 10.1002/anie.201301167

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© 2013 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.

Re-use of this article is permitted in accordance with the Creative Commons Deed, Attribution 2.5, which does not permit commercial exploitation.

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Scheme 3 — Effect of isotope substitution on product distribution. Reaction conditions: i) B₂pin₂ (1.3 equiv), Pd(OAc)₂ (2 mol %), BQ (1.1 equiv), DCE, 50 °C, 15 h. ii) B₂pin₂ (1.3 equiv), Pd(OAc)₂ (5 mol %), BQ (1.1 equiv), DCE, 50 °C, 15 h. E=CO₂Me.