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. Author manuscript; available in PMC: 2014 Jul 26.
Published in final edited form as: J Chromatogr A. 2013 Apr 18;1300:217–226. doi: 10.1016/j.chroma.2013.04.030

Table 3.

Comparison of metabolites from methanol precipitation (MeOH) and MTBE extraction (MTBE) on RPC and HILIC column in both positive and negative ionization mode.

MeOH MTBE Common
features
(%)a
Unique in
MeOH
Unique in
MTBE
RP-Positive Mode 1410 1828 560 (31%) 850 1268
RP-Negative Mode 512 619 325 (53%) 187 294
HILIC-Positive Mode 1669 1297 685 (53%) 984 612
HILIC-Negative Mode 467 271 203 (75%) 264 68

a

The percentage of common is calculated by the number in common vs numbers in MTBE extraction.