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. Author manuscript; available in PMC: 2013 Aug 11.
Published in final edited form as: Angew Chem Int Ed Engl. 2010 Aug 16;49(35):6151–6155. doi: 10.1002/anie.201002293

Scheme 1.

Scheme 1

Retrosynthesis outline for accessing peloruside A (1). BPS = tert-butyldiphenylsilyl; MOM = methoxymethyl; PMB = para-methoxybenzyl; RCM = ring-closing metathesis; TBS = tert-butyldimethylsilyl.