Table 2. Description of the exponential change (y = b × ek × age) in whole dissolved organic carbon (DOCSum) in mg L-1, colloidal associated iron (Fecoll) in μg L-1, absorbance at wavelengths (λ) 420 and 254 nm (Aλ) (unitless but over path length of 1 m), specific absorbance (SUVAλ) in L mg C-1 m-1, DOC estimated to be from internal microbial (DOCFI_auto) and external terrestrial (DOCFI_import) sources in mg L-1 based on the fluorescence index (FI), the humification index (HIX) and the freshness index (β: α), across the main lake basins (passing from A to F, excluding basin D), including the adjusted R 2, the significance level, (*** p < 0.0001, ** p < 0.001, * p < 0.05), number of sites across the lake (n), the amount of a variable at a water residence time of 0 (t0), and 2.8 (t2.8) years, the net change within the lake (Δ in lake), and the half-life (t1/2) (full details of fitting parameters b and k provided in Table S3 in File S1, as well as results of molecular weight size classes).
| b | k | adj. R2 | sig.-level | n | t0 | t2.8 | Δ in lake | t1/2 | |
|---|---|---|---|---|---|---|---|---|---|
| DOCSum | 10.5 | 0.114 | 0.82 | *** | 17 | 10.5 | 7.7 | -2.9 | -6.1 |
| Fecoll | 312 | -1.09 | 0.80 | *** | 17 | 312 | 15 | 297 | -0.6 |
| A420 | 3.3 | 0.418 | 0.86 | *** | 17 | 3.26 | 1.01 | -2.25 | -1.7 |
| A254 | 0.4 | 0.255 | 0.89 | *** | 17 | 0.41 | 0.20 | -0.21 | -2.7 |
| SUVA420 | 0.3 | 0.307 | 0.86 | *** | 17 | 0.31 | 0.13 | -0.18 | -2.3 |
| SUVA254 | 4.1 | 0.255 | 0.89 | *** | 17 | 4.11 | 2.01 | -2.10 | -2.7 |
| DOCFI_auto | 2.5 | 0.067 | 0.67 | *** | 16 | 2.49 | 3.01 | 0.51 | 10.4 |
| DOCFI_import | 8.0 | 0.182 | 0.89 | *** | 17 | 7.95 | 4.78 | -3.17 | -3.8 |
| FI | 1.3 | 0.021 | 0.82 | *** | 17 | 1.35 | 1.43 | 0.08 | |
| HIX | 0.9 | 0.009 | 0.42 | ** | 17 | 0.89 | 0.87 | -0.02 | |
| β:α | 0.5 | 0.079 | 0.90 | *** | 17 | 0.52 | 0.65 | 0.13 | |
| %Very Large | 1.0 | 0.788 | 0.61 | ** | 17 | 1 | 0 | -1 | |
| % Large | 24.4 | 0.139 | 0.75 | *** | 17 | 24 | 17 | -8 | |
| %Medium | 74.5 | 0.062 | 0.83 | *** | 17 | 75 | 89 | 14 | |
| %Small | 90.7 | 0.240 | 0.06 | no fit | 17 | − | − | − |