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. Author manuscript; available in PMC: 2014 Jun 26.
Published in final edited form as: J Am Chem Soc. 2013 Jun 12;135(25):9358–9361. doi: 10.1021/ja4047312

Table 3.

Scope of π-nucleophile, selectivity of olefin transposition

graphic file with name nihms492816t3.jpg
a

R = 1-naphthyl.

b

Determined by chiral HPLC analysis of the alcohol or aryl ester. Diastereoselectivities determined by 1H-NMR analysis.

c

Determined by 1H-NMR analysis using an internal standard.